Why essential oil and hydrolat are not the only distillation products?

We know distillation as the method of producing essential oil and its side product, hydrolat or aromatic water. But we often overlook that those are not the only distillation products. There are two additional products we do not hear much about in the phytotherapeutic world: residual plant material and residual distillation water. They are quite valuable from the environmental perspective and present a problem as well as a challenge for the distillation industry.

 

In fact, distillation is a very specific method for extracting bioactive compounds. Besides volatiles, aromatic plants produce a variety of non-volatile secondary metabolites which cannot be distilled into essential oil or hydrolat. On average, only about 1% of dry plant mass is extracted by distillation, and everything else is simply lost and thrown away.

 

global production of essential oil was 180 000 tons in 2015 and is predicted to reach 370 000 tons by 2024, with 8.4% annual growth. Imagine all the resources needed for growing plants and distilling such amounts of essential oil.

By introducing the four distillation products, my goal is to put distillation into a wider context and re-think it from an environmental perspective.

 

 

1. ESSENTIAL OIL

Essential oils are the main products of distillation of essential oil distiller. Essential oils are mixtures of volatile lipophilic compounds from plants and are used in the food, pharmaceutical, cosmetic and perfume industries, and in aromatherapy.

 

2. HYDROLAT

Hydrolat (hydrosol, aromatic water) is the distilled water enriched with plant volatiles. It’s misleading to think of it as water saturated with essential oil, as the composition of its aromatic fraction (usually between 0,001% and 0,1%) typically differs quite a bit from the corresponding essential oil. Thus hydrolat is an independent distillation product.

 

Essential oil industry traditionally treated hydrolats as distillation by-products, discarding them or re-distilling to increase the yield of essential oils. However, in the last 15 years, they have witnessed a drastic increase in popularity. Many home distillers, as well as professional producers, distil them as their primary products, aimed for use in aromatherapy and natural cosmetics.

 

3. RESIDUAL PLANT MATERIAL

The distilled plant material is commonly treated as a waste without economic value. It can be used as animal feed, energy resource, or for soil replenishment. The latter poses a specific challenge, as the antimicrobial activity of the residue may prolong decomposition time and affect its microbial structure.

 

Lavender and lavandin straws, for example, can be used in mulching around trees, vineyards and horticultural crops to maintain soil moisture and restrict the growth of certain weeds or pathogenic organisms. However, distillers usually produce far more significant amounts than that, and not all materials may be suitable for mulching.

 

To put it into a perspective of how much material we’re talking about: one kilo of fresh rose flowers produces two kg of wet residual material. For one kg of essential oil, we need about 3-4 tons of flowers, which yields about 6-8 tons of the residual matter.

In India alone, about 3 million tons of residual material is produced each year, which then typically rots and decomposes in the fields. Due to lack of suitable disposal surfaces and stricter regulations – while facing continuously increasing demand for essential oil – it is clear that this is becoming a problem, a burden not only for the distilleries but the environment as well.

 

Patchouli has been one of the model plants for research in this regard. It was shown to be suitable for vermicomposting: with the right combination of microorganisms and earthworms, the residual material can decompose into humus in less than 100 days. Humus is rich in nutrients and beneficial microorganisms and can be used to enrich soil with minerals, optimize its pH value and increase water retention capacity, while reducing consumption of additional fertilizers and fungicides. In a field experiment, the patchouli crop treated with the patchouli vermicompost had up to 60% higher yield of essential oil, compared to standard chemical fertilizer .

 

On the other hand, many biologically active substances are still present in the residual matter. They can be further extracted by additional extraction methods and used, for example, as antioxidants in the food and pharmaceutical industry. For example, plants from the mint family (Lamiaceae) such as rosemary, thyme, oregano, mint, basil, lemon balm and sage, produce phenolic compounds with a broad spectrum of biological activity:

 

  • Residual sage (Salvia officinalis) contains significant amounts of valuable flavonoids (apigenin and luteolin). Its water and ethanolic extracts retain antioxidative, antibacterial and antifungal activity.
  • Residual lavandin (Lavandula x intermedia) and spike lavender (Lavandula latifolia) are rich sources of phenolic compounds, such as phenolic acids and flavonoids, many of which are strong antioxidants and antimicrobials . 34 volatile constituents were identified in lavandin, including considerable amounts of coumarins with potential economic value.
  • Extracts of residual rosemary (Rosmarinus officinalis), savory and oregano species are also a good source of natural antioxidants, especially phenolic acids such as caffeic and rosmarinic acid, and a  phenolic diterpene carnosic acid .
  • From the residual clary sage (Salvia sclarea), a diterpene sclareol can be extracted, which is an important precursor for the synthesis of ambrox, the crucial aromatic compound in ambergris and a staple in the contemporary perfume industry.

 

Thus, a two-level approach may be an optimal solution: first, extraction of useful compounds and then composting.

The need for more efficient and environmentally friendly extraction encourages the development of new methods and technologies. Many alternative approaches are currently studied, such as the use of green solvents as an alternative to traditional organic solvents with potential health and environmental risks, or energy efficient extraction methods employing ultrasound, microwaves, electric fields, or pressure manipulation. These new technologies will likely have a significant impact on the industry of natural compounds extraction, which is already happening in the case of CO2 (supercritical) extracts.

 

4. RESIDUAL WATER

The residual distillation water is mainly produced in water distillation, where plant material comes in direct contact with water, and in smaller amounts in steam distillation.

Large amounts of residual water are produced in the rose distillation industry because rose is one of a few plants of highest economic significance where water distillation is employed. Each distillation of 500-1000 kg rose petals produces 4000 litres of residual water that contains high amounts of poorly degradable polyphenols and should, therefore, be treated as a biopollutant . However, an extracted fraction rich in quercetin, kaempferol and ellagic acid was found to be a potent tyrosinase inhibitor and could be used as an active cosmetic ingredient for reducing hyperpigmentation.

 

Searching for natural sources of antioxidants is a prospective research field, relevant primarily for the food and cosmetics industry, where the two common synthetic antioxidants BHA and BHT turned out as inappropriate for long-term use and may even have carcinogenic activity.

 

The experiment incorporated the residual water of rosemary, sage and thyme into marinades for turkey thighs. Antioxidants contained in the residues decreased lipid oxidation and inhibited the development of rancid off-flavours in stored meat. Interestingly, the residual waters were found to be more powerful antioxidants than the corresponding hydrolats.

 

Perhaps even more intriguing, greenhouse experiments indicate that residual waters from certain aromatic plants (foliar application) can influence biosynthesis of terpenes as well as the yield of essential oil. For example, the residual rosemary water increased synthesis of l-limonene in peppermint, while the residual lemon balm water decreased menthofuran and increased menthyl acetate production. While these are indeed interesting observations, more experimentation is needed to elucidate whether (and how) re-use of some of these waters may be employed in practice.

 

IS USING ESSENTIAL OILS ALWAYS REASONABLE?

We’re easily charmed by data showing how much plant material is needed to produce one kilo or even a drop of essential oil. But do we also realise how much of the good stuff is simply thrown away, only to take that one percent (often much less) of volatiles?

When we think of ourselves how ecologically aware we are because we tend to use natural home-made cleaning products based on essential oils instead of aggressive chemicals, or how recklessly we may consume them at every opportunity (or are advised to do so by aggressive sellers) – let’s also think for a moment how wasteful distillation really is.

Depletion of natural resources of medicinal and aromatic plants (such as rosewood, spikenard or frankincense) is a serious problem in its own right. With increasing awareness and stricter regulations, more and more essential oils are comming from renewable resources. However, we need to acknowledge that even renewable resources are basically monoculture plantations that are eating away natural ecosystems.

It is of course not my intention to discourage the use of essential oils but to encourage to use them wisely and be open to new perspectives offered by innovative extraction technologies. We should be aware of the downsides but think about all four distillation products as research and business opportunities.

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